Tris(biacetyl dihydrazone-κ2N,N′)cadmium(II) bis(perchlorate) at 110 K
✍ Scribed by Tirosh, Einat ;Maman, Rozi ;Goldberg, Israel
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 165 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Cd(C 24 H 27 N 7 )](ClO 4 ) 2 , the Cd 2+ ion is coordinated by six N atoms from the tripodal organic ligand in the form of a trigonal antiprism.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.085 wR factor = 0.168 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Cd(C 2 H 8 N 2 ) 3 ][Cu(C 4 N 2 S 2 ) 2 ], the Cd II atom has a distorted octahedral geometry. The Cu II atom is in a distorted square-planar geometry. Both ions lie on twofold rotation axes. They are not connected covalently.