✦ LIBER ✦

Tris(2,2′-biimidazole)nickel(II) phthalate

✍ Scribed by Yang, Li-Ning ;Li, Jun ;Zhang, Feng-Xing

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 332 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805030941

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✦ Synopsis

A novel three-dimensional hydrogen-bonded complex, [Ni(C 6 H 6 N 4 ) 3 ](C 8 H 4 O 4 ), was synthesized. Each Ni atom is six-coordinate, in a pseudo-octahedral geometry, formed by six N atoms of three chelating biimidazole ligands. It has a three-dimensional network structure, formed by extensive hydrogen bonds between [Ni(H 2 biim) 3 ] 2+ cations and phthalate anions. There are two cations and two anions in the asymmetric unit.

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