Aquabis(2,2′-biimidazole)copper(II) dinitrate
✍ Scribed by Sang, Ruili ;Xu, Li
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 361 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The crystal structure of the title compound, [Cu(C 6 H 6 N 4 ) 2 -(H 2 O)](NO 3 ) 2 , has been determined from single-crystal X-ray diffraction data. The five-coordinate geometry of the copper(II) centre comprises four N atoms from two biimidazole ligands and a water molecule in a distorted squarebased pyramidal coordination. Cu and the aqua ligand lie on a twofold rotation axis.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 296 K Mean (C-C) = 0.005 A R factor = 0.051 wR factor = 0.148 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Each Cu atom in the centrosymmetric dinuclear title compound, [Cu 2 (C 3 H 5 O 5 P) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ], is chelated by an N-heterocycle and is also coordinated by a molecule of water. The two Cu atoms are bridged by the 3-phosphonopropionate(2À) unit, giving rise to a square-pyramidal g
l-N,N 0 0 0 -Bis(3-aminopropyl)oxamidato(2À)]bis[(2,2 0 0 0 -bipyridine)copper(II)] dinitrate