Tris(2-methyl-2-phenylpropyl)(pyridine-3-carboxylato)tin(IV)
✍ Scribed by Tian, Lai-Jin ;Sun, Yu-Xi ;Yang, Min ;Yang, Guo-Ming
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 85 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The Sn atom of the title compound, [Sn(C 10 H 13 ) 3 (C 6 H 4 NO 2 )], is four-coordinate and possesses a distorted tetrahedral geometry.
metal-organic papers
Acta Cryst. (2005). E61, m1346-m1347 Tian et al. [Sn(C 10 H 13 ) 3 (C 6 H 4 NO 2 )] m1347
📜 SIMILAR VOLUMES
The crystal structure of the title complex, [Sn(C 4 H 9 ) 3 (C 6 H 3 -ClNO 3 )], possesses an infinite two-dimensional polymeric chain structure in the solid state, resulting from strong intermolecular N-HÁ Á ÁO hydrogen bonds. The Sn atom is five-coordinate with a distorted trigonal bipyramidal geo
The Sn atom of the title compound, [Sn(C 10 H 13 ) 3 (C 7 H 3 N 2 O 7 )], is four-coordinate and possesses a distorted tetrahedral geometry. There is an intramolecular O-HÁ Á ÁO hydrogen bond between the carboxyl and the phenolic hydroxy groups.
The title compound, [Sn(C~10~H~13~)~3~(C~7~H~6~NO~2~)], crystallizes with two independent molecules in the asymmetric unit. The Sn atom is four-coordinate and has a distorted SnC~3~O tetrahedral geometry. N—H...O hydrogen bonds help to establish the crystal packing.
The six-coordinate Sn atom (site symmetry 2) in the monomeric title complex, [Sn(CH 3 ) 2 (C 6 H 4 NO 3 ) 2 ], exists in a skew-trapezoidal geometry ].