The Sn atom of the title compound, [Sn(C 10 H 13 ) 3 (C 6 H 4 NO 2 )], is four-coordinate and possesses a distorted tetrahedral geometry. ## metal-organic papers Acta Cryst. (2005). E61, m1346-m1347 Tian et al. [Sn(C 10 H 13 ) 3 (C 6 H 4 NO 2 )] m1347
Tri-n-butyl(5-chloro-6-hydroxypyridine-3-carboxylato)tin(IV)
✍ Scribed by Li, Fa-Hui ;Yin, Han-Dong ;Li, Gang ;Wang, Da-Qi
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 91 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The crystal structure of the title complex, [Sn(C 4 H 9 ) 3 (C 6 H 3 -ClNO 3 )], possesses an infinite two-dimensional polymeric chain structure in the solid state, resulting from strong intermolecular N-HÁ Á ÁO hydrogen bonds. The Sn atom is five-coordinate with a distorted trigonal bipyramidal geometry.
📜 SIMILAR VOLUMES
In the title compound, C 14 H 16 ClN 7 O 2 , the triazole ring carries cyano and formamidine substituents and is bound via a methylene bridge to a chloropyridine unit. There is evidence of significant electron delocalization in the triazolyl system. Intramolecular O-HÁ Á ÁO and intermolecular C-HÁ Á
In the title molecule, C 26 H 23 Cl 2 NO 3 S, the tetrahydropyridine ring adopts a half-chair conformation. Intramolecular O-HÁ Á ÁO hydrogen bonding generates an S(6) ring motif. Intermolecular N-HÁ Á ÁCl, C-HÁ Á ÁCl and C-HÁ Á ÁS hydrogen bonding generates primary graph-set motifs C(8), C(11) and