The crystal structure of the title complex, [Sn(C 4 H 9 ) 3 (C 6 H 3 -ClNO 3 )], possesses an infinite two-dimensional polymeric chain structure in the solid state, resulting from strong intermolecular N-HÁ Á ÁO hydrogen bonds. The Sn atom is five-coordinate with a distorted trigonal bipyramidal geo
Bis(3-hydroxypyridine-2-carboxylato)dimethyltin(IV)
✍ Scribed by Tian, Guang-Ru ;Zhang, Ru-Fen ;Ma, Chun-Lin ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 141 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The six-coordinate Sn atom (site symmetry 2) in the monomeric title complex, [Sn(CH 3 ) 2 (C 6 H 4 NO 3 ) 2 ], exists in a skew-trapezoidal geometry ].
📜 SIMILAR VOLUMES
The Sn atom of the title compound, [Sn(C 10 H 13 ) 3 (C 6 H 4 NO 2 )], is four-coordinate and possesses a distorted tetrahedral geometry. ## metal-organic papers Acta Cryst. (2005). E61, m1346-m1347 Tian et al. [Sn(C 10 H 13 ) 3 (C 6 H 4 NO 2 )] m1347
Single-crystal X-ray study T = 170 K Mean '(C±C) = 0.007 A Ê Disorder in main residue R factor = 0.050 wR factor = 0.148 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.