Tris(1H-inden-1-yl)phosphane
✍ Scribed by Cantrell, Timothy ;Perrotin, Philippe ;Twamley, Brendan ;Shapiro, Pamela J.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 148 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the structure of the title compound, C 27 H 21 P, at 89 (2) K the P atom is bound to the allylic carbon of the indenyl unit with P-C distances of ca 1.88 A ˚.
📜 SIMILAR VOLUMES
## Abstract ^1^H, ^13^C and two‐dimensional NMR analyses were applied to determine the NMR parameters of 6‐(2′,3′‐dihydro‐1′__H__‐inden‐1′‐yl)‐1__H__‐indene. The measurements were accomplished with 0.5 mg of the substance, this quantity being sufficient to determine the chemical shifts of all the H
In the title compound, [Fe(C 5 H 5 )(C 20 H 23 )], the two fivemembered cyclopentadienyl rings are nearly parallel, with a dihedral angle of only 3.8 (1) . The dihedral angle between the indenyl plane and the substituted cyclopentadienyl ring is 58.1 (2) .
The title centrosymmetric complex, [Mo 2 (C 19 H 19 )(CO) 6 ] or [{( 5 -C 5 H 4 )C(CH 2 ) 4 (C 9 H 7 )}Mo(CO) 3 ] 2 , is a binuclear metal carbonyl complex containing an Mo-Mo single bond [3.2405 (9) A ˚]. The cyclopentane ring adopts an envelope conformation. The dihedral angle between the indene a