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1-Ferrocenyl-1-(1-inden­yl)cyclo­hexa­ne

✍ Scribed by Lin, Jin ;Xu, Shan-Sheng ;Song, Hai-Bin

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
148 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Fe(C 5 H 5 )(C 20 H 23 )], the two fivemembered cyclopentadienyl rings are nearly parallel, with a dihedral angle of only 3.8 (1) . The dihedral angle between the indenyl plane and the substituted cyclopentadienyl ring is 58.1 (2) .

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The title centrosymmetric complex, [Mo 2 (C 19 H 19 )(CO) 6 ] or [{( 5 -C 5 H 4 )C(CH 2 ) 4 (C 9 H 7 )}Mo(CO) 3 ] 2 , is a binuclear metal carbonyl complex containing an Mo-Mo single bond [3.2405 (9) A ˚]. The cyclopentane ring adopts an envelope conformation. The dihedral angle between the indene a

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In the molecule of the title compound, C 18 H 21 F 2 N 3 , the 1,3,5triazacyclohexane ring has a chair conformation. Intramolecular C-HÁ Á ÁF and C-HÁ Á ÁN hydrogen bonds may be effective in the stabilization of the structure.