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Bis{[1-(1H-inden-3-yl)cyclo­pent­yl]-η5-cyclo­penta­dien­yl}hexa­carbonyl­dimolydenum(I)(Mo—Mo)

✍ Scribed by Lin, Jin ;Song, Hai-Bin ;Xu, Shan-Sheng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
121 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title centrosymmetric complex, [Mo 2 (C 19 H 19 )(CO) 6 ] or [{( 5 -C 5 H 4 )C(CH 2 ) 4 (C 9 H 7 )}Mo(CO) 3 ] 2 , is a binuclear metal carbonyl complex containing an Mo-Mo single bond [3.2405 (9) A ˚]. The cyclopentane ring adopts an envelope conformation. The dihedral angle between the indene and cyclopentadiene rings is 57.0 (2) .

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In the title structure, [CoRu(C 10 H 20 )Cl(C 17 H 14 P) 2 ]PF 6 Á-0.5CH 2 Cl 2 , the Ru atom is coordinated by a pentamethylcyclopentadienyl ring, one Cl atom and two P atoms of the chelating 1,1 0 -bis(diphenylphosphino)cobaltocenium ligand, giving a three-legged piano-stool geometry. The solvent