Triphenylphosphane complexes of copper(I): Structural and 31P NMR investigations
✍ Scribed by Thomas Kräuter; Bernhard Neumüller
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 598 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0277-5387
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📜 SIMILAR VOLUMES
NH2(CH&CH3 and (for Pt) C2H4. For both metals, the NMR. parameters depend on the trans-influence of the ligand L. The values 1J(195Pt, 15N) vary from 138 to 336 Hz and can be shown to correlate with the values 1J(195Pt, 31P) in the complexes trans-[PtCl,(PBu!j)L]. There is a linear relation between
## Abstract Rhodium(I) complexes containing chiral chelating diphosphines, e.g. __R__,__R__‐dipamp [(__R__,__R__)‐1,2‐bis(__o__‐methoxy‐phenylphenylphosphino)ethane] or __S__,__S__‐chiraphos [(2__S__,3__S__)‐bis(diphenylphosphino)butane] and a prochiral olefin, e.g. methyl (__Z__)‐α‐acetamidocinnam