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Structural and Theoretical Studies of ortho-Substituted Triphenylphosphane Ligands and Their Rhodium(I) Complexes

✍ Scribed by Pekka Suomalainen; Sirpa Jääskeläinen; Matti Haukka; Riitta H. Laitinen; Jouni Pursiainen; Tapani A. Pakkanen

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
312 KB
Volume
2000
Category
Article
ISSN
1434-1948

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## Abstract Density functional calculations are reported for complexes of general formula [(carbene)RhClL~2~] featuring model phosphino‐ and aminocarbenes. Both the __cis__ and __trans__ isomers of the rhodium(I) η^1^‐complexes (**1**–**9**) were investigated, and the influence of the rhodium co‐li