P NMR spectra of several inorganic phosphates have been examined both in the crystalline and the glassy states. The parameter (Z,&)q clearly demarcates ortho-, pyro-and meta-phosphates in terms of the "P chemical shifts. Based on such a diagram, inorganic phosphate glasses are found to consist essen
31P MAS NMR Investigations of Crystalline and Glassy NASICON-Type Phosphates
β Scribed by K.C. Sobha; K.J. Rao
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 229 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0022-4596
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π SIMILAR VOLUMES
High microwave susceptibility of NaH 2 PO 4 β’2H 2 O has been discovered. This hydrated acid phosphate of sodium can be heated upto 1000 K or more when exposed to 2.45 GHz microwaves. Using this, a novel microwave-assisted preparation of a number of important crystalline and glassy materials with NAS
The rotational dynamics of P O S and P O in the solid state were studied by means of 31 P NMR spectra of spinning and 4 6 4 7 static powder samples in the temperature range of 153-295 K and 295-388 K, respectively. All spectra were simulated to confirm the type of the motion and to extract the time
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