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Triphenyl­benzyl­phospho­nium trichloro­(propiononitrile)platinate(II)

✍ Scribed by Luzyanin, Konstantin V. ;Haukka, Matti ;Izotova, Yulia A. ;Pombeiro, Armando J.L. ;Kukushkin, Vadim Yu.


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
175 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title platinum(II) propiononitrile complex, [Ph 3 PCH 2 Ph][PtCl 3 (EtCN)], the coordination polyhedron of the metal center is slightly distorted square planar.


📜 SIMILAR VOLUMES


Synthesis and structural characterizatio
✍ Renzo Cini; Alessandro Donati; Rovena Giannettoni 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 161 KB

The addition of a solution of terpy (2,2%;6%,2¦-terpyridine) to a solution of cis-[PtCl 2 (dmso) 2 ] (dmso, dimethylsulfoxide) in acetone, at 25°C, brought to the formation of [PtCl(terpy)][PtCl 3 (dmso)] (1), as a high yield crystalline red powder, within 12 h. Single crystals of 1 suitable for X-r