Triphenylbenzylphosphonium trichloro(propiononitrile)platinate(II)
✍ Scribed by Luzyanin, Konstantin V. ;Haukka, Matti ;Izotova, Yulia A. ;Pombeiro, Armando J.L. ;Kukushkin, Vadim Yu.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 175 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title platinum(II) propiononitrile complex, [Ph 3 PCH 2 Ph][PtCl 3 (EtCN)], the coordination polyhedron of the metal center is slightly distorted square planar.
📜 SIMILAR VOLUMES
Tetrakis(2-pyridyl)pyrazine]bis-[chloroplatinum(II)] bis[trichloro(dimethyl sulfoxide-jS)platinate(II)]
The addition of a solution of terpy (2,2%;6%,2¦-terpyridine) to a solution of cis-[PtCl 2 (dmso) 2 ] (dmso, dimethylsulfoxide) in acetone, at 25°C, brought to the formation of [PtCl(terpy)][PtCl 3 (dmso)] (1), as a high yield crystalline red powder, within 12 h. Single crystals of 1 suitable for X-r