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Trimethylsilylierte bicyclobutan-2,4-dicarbonsäureanhydride [1]

✍ Scribed by Hans Werner Lage; Hans Peter Reisenauer; Günther Maier


Book ID
104221178
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
174 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis


Irradlatlon of tr~methylsllylated cyclobutene dlcarboxyllc anhydrldes leads to the corresponding bLcyclobutane derlvatlves. Desllylatlon yields blcyclobutane dlcarboxyllc anhydrIde Cq), which on photoexcltatlon 1n an argon matrix at 10 K does not give tetrahedrane but cyclobutadlene instead

Das Zlel, uber trlmethylsllyl~erte Vorstufen zum unsubstltulerten Tetrahedran zu kommen,


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