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Triisopropylsilanol: A new type of phase transfer catalyst for dehydrohalogenation

โœ Scribed by John A. Soderquist; Jaime Vaquer; Michael J. Diaz; Anil M. Rane; Frederick G. Bordwell; Shizhong Zhang


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
241 KB
Volume
37
Category
Article
ISSN
0040-4039

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A new active catalyst species for enanti
โœ Martin J. O'Donnell; Shengde Wu; John C. Huffman ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 900 KB

This paper briefly reviews the use of Schiff base substrates in amino acid synthesis. Recent studies lead to the proposal of a new active catalyst species (12) for the asymmetric PTC alkylation of active methylene compounds (2). Mechanistic implications are detailed.