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A new active catalyst species for enantioselective alkylation by phase-transfer catalysis

✍ Scribed by Martin J. O'Donnell; Shengde Wu; John C. Huffman

Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 900 KB
Volume: 50
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)89382-0

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✦ Synopsis

This paper briefly reviews the use of Schiff base substrates in amino acid synthesis. Recent studies lead to the proposal of a new active catalyst species (12) for the asymmetric PTC alkylation of active methylene compounds (2). Mechanistic implications are detailed.

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