Lacunary Keggin type polyoxotungstates in conjunction with a phase transfer catalyst: An effective catalyst system for epoxidation of alkenes with aqueous H2O2

[SbW9O33]-based polyoxometalate combined

[SbW9O33]-based polyoxometalate combined with a phase transfer catalyst: A highly effective catalyst system for selective oxidation of alcohols with H2O2, and spectroscopic investigation

✍ Rohit H. Ingle; N.K. Kala Raj; P. Manikandan 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 379 KB

Na 9 [SbW 9 O 33 ] in conjunction with a phase transfer catalyst, methyltricapryl ammonium chloride, is highly efficient for selective oxidation of variety of alcohols with aq. H 2 O 2 to yield corresponding carbonyls. Most importantly the reactions are carried out in the absence of any organic solv