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(Tricyclo­hexyl­phosphine)bis­(tropolonato)palladium(II)

✍ Scribed by Steyl, Gideon

Book ID
104486715
Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
198 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

A new type of -diketone palladium(II) complex containing a tertiary phosphine, namely the title compound, [Pd(C 7 H 5 O 2 ) 2 -(C 18 H 33 P)], crystallizes with a square-planar geometry about the palladium(II) metal centre. One tropolonate ligand is bonded in a bidentate chelating mode, while the second one is bonded through a single O atom to the palladium(II) metal centre. The Pd-O distances range from 1.9907 (13) to 2.0702 (12) A ˚, and the O-Pd-O bite angle for the bidentate tropolonate ligand is 80.30 (5) .

📜 SIMILAR VOLUMES

Bis(tropolonato)palladium(II)
Bis(tropolonato)palladium(II)
✍ Steyl, Gideon 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 123 KB

A new type of highly symmetrical -diketone palladium(II) complex, bis(tropolonato)palladium(II) (tropolone = 2-hydroxy-2,4,6-cycloheptatrienone), [Pd(C 7 O 2 H 5 )], crystallizes in a square-planar geometry with one molecule in the asymmetric unit. The Pd-O bond distances and O-Pd-O internal angles

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✍ Berg, J.-E. ;Pilotti, A.-M. ;Söderholm, A.-C. ;Karlsson, B. 📂 Article 📅 1978 🏛 International Union of Crystallography ⚖ 211 KB