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Bis(tropolonato)copper(II)

✍ Scribed by Berg, J.-E. ;Pilotti, A.-M. ;Söderholm, A.-C. ;Karlsson, B.


Book ID
114525487
Publisher
International Union of Crystallography
Year
1978
Weight
211 KB
Volume
34
Category
Article
ISSN
0567-7408

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Bis(tropolonato)palladium(II)
✍ Steyl, Gideon 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 123 KB

A new type of highly symmetrical -diketone palladium(II) complex, bis(tropolonato)palladium(II) (tropolone = 2-hydroxy-2,4,6-cycloheptatrienone), [Pd(C 7 O 2 H 5 )], crystallizes in a square-planar geometry with one molecule in the asymmetric unit. The Pd-O bond distances and O-Pd-O internal angles

(Tricyclo­hexyl­phosphine)bis­(tropolona
✍ Steyl, Gideon 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 198 KB

A new type of -diketone palladium(II) complex containing a tertiary phosphine, namely the title compound, [Pd(C 7 H 5 O 2 ) 2 -(C 18 H 33 P)], crystallizes with a square-planar geometry about the palladium(II) metal centre. One tropolonate ligand is bonded in a bidentate chelating mode, while the se