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Bis(tropolonato)palladium(II)

✍ Scribed by Steyl, Gideon

Book ID
104485051
Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
123 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

A new type of highly symmetrical -diketone palladium(II) complex, bis(tropolonato)palladium(II) (tropolone = 2-hydroxy-2,4,6-cycloheptatrienone), [Pd(C 7 O 2 H 5 )], crystallizes in a square-planar geometry with one molecule in the asymmetric unit. The Pd-O bond distances and O-Pd-O internal angles lie in the ranges 1.969 (2)-2.002 (2) A ˚and 81.83 (9)-99.28 (9) , respectively. Weak intermolecular C-HÁ Á ÁO hydrogen bonds link the essentially planar molecules into ribbons extending along the a axis.

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