Regioselective generation of the C(2)-carbocation a of tricyc10[4.2.2.0',~]decane (1) by treatment of both corresponding epimeric alcohols 5 and 6 with BF, and trapping the rearranged tricy~lo[S.3.0.O~~~]decan-7-yl carhocation b with Et,SiH as hydride-ion donor (ionic hydrogenation) gives the corres
โฆ LIBER โฆ
Tricyclo[4.2.2.01,6]decane-tricyclo[4.2.2.01,5]decane interconversions. [4.2.2]propellane rearrangements and a nonphotochemical propellane synthesis
โ Scribed by Eaton, Philip E.; Jobe, Patrick G.; Nyi, Kayson
- Book ID
- 126267919
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 350 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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