The addition of dihalocarbenes to norbornene and Its derivatives produces an lntermdiate which Imdergoes a cyclopropyl-ally1 rearrangement. (2) The gem-dihalocyclopropane, Isolated in
Tricyclo[4.2.1.01,6]non-3-ene(I) and tricyclo[4.2.1.01,6]nonane(II) -two new strained propellanes
β Scribed by Philip Warner; Richard LaRose
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 250 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Considerable effort is being expended toward the understanding of the nature of strained carbon-carbon single bonds.2 In this respect, strained propellanes are very 1nstructive.e We wish to report syntheses for and reactivities of two new C4.2.11 propellanes; we feel the results contribute
π SIMILAR VOLUMES
Im folgenden beschreiben wir die Synthese des ( I ) entsprechenden anti-1,6 ; 8,13-Bismethano-7,14-dihydro-[14lannulens (8) sowie einige seiner Umwandlungen. Als Ausgangsverbindung diente 1,4,5,8,9,10-Hexahydroanthracen (4) [21, fur dessen Darstellung durch die Reduktion von 9,IO-Dihydroanthracen mi