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Tricyclo[4.3.1.01,6]deca-2,4-dienetricarbonyl-chromium, a Homoaromatic Transition Metal Complex

✍ Scribed by Dr. Wolf-Eckhard Bleck; Priv.-Doz. Dr. Wolfram Grimme; Priv.-Doz. Dr. Harald Günther; Prof. Dr. Emanuel Vogel


Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
266 KB
Volume
9
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Crystal Structure of Tricarbonyl Complex
✍ R. L. Beddoes; P. F. Lindley; O. S. Mills 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 240 KB 👁 2 views

downfield. Thus on complex formation of (/), additional shielding and deshielding effects occur which can be explained in terms of a diamagnetic ring current in complex (2). We therefore propose the homoaromatic structure (2a) for the complex. Further support for this assignment comes from the fact

Tricyclo[4.3.1.01,6]deca-2,4,7-trien, ei
✍ Dr. W. Grimme; M. Kaufhold; cand. chem. U. Dettmeier; Prof. Dr. E. Vogel 📂 Article 📅 1966 🏛 John Wiley and Sons 🌐 English ⚖ 262 KB 👁 1 views

Im folgenden beschreiben wir die Synthese des ( I ) entsprechenden anti-1,6 ; 8,13-Bismethano-7,14-dihydro-[14lannulens (8) sowie einige seiner Umwandlungen. Als Ausgangsverbindung diente 1,4,5,8,9,10-Hexahydroanthracen (4) [21, fur dessen Darstellung durch die Reduktion von 9,IO-Dihydroanthracen mi