The Adamantane Rearrangement of Tricyclo
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Kanai L. Ghatak; Camille Ganter
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Article
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1988
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John Wiley and Sons
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German
β 345 KB
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Regioselective generation of the C(2)-carbocation a of tricyc10[4.2.2.0',~]decane (1) by treatment of both corresponding epimeric alcohols 5 and 6 with BF, and trapping the rearranged tricy~lo[S.3.0.O~~~]decan-7-yl carhocation b with Et,SiH as hydride-ion donor (ionic hydrogenation) gives the corres