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Tricarbonyl Rhenium(I) and Technetium(I) Complexes with Hydrazones Derived from 4,5-Diazafluoren-9-one and 1,10-Phenanthroline-5,6-dione

✍ Scribed by Paula Barbazán; Adelheid Hagenbach; Elisabeth Oehlke; Ulrich Abram; Rosa Carballo; Sabina Rodríguez-Hermida; Ezequiel M. Vázquez-López


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
713 KB
Volume
2010
Category
Article
ISSN
1434-1948

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✍ Shin-ichi Nakatsuka; Kumi Yoshida; Toshio Goto 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 238 KB

Regiospecific cyclization of the alcohol &into the bicyclo[ 4.2.21 compound g was achieved via selective activation of the secondary methoxy group and subsequent acid treatment. A side-chain was introduced at the bridge-head position, thus making up the bicyclomycin skeleton. Bicyclomycin, which i