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Dimerization of cyclopentadienyl ligands in the synthesis of transition metal complexes. 1,4,5,6,7,10,11,12-Octamethyltricyclo[7.3.0.03,7]-dodeca-3,5,9,11-tetraene and the complex of 1,1′,3,3′-tetrakis-(tert-butyl)-1,1′-dihydrofulvalene with I3−

✍ Scribed by V. K. Belsky; A. V. Khvostov; Yu. K. Gun'ko; B. M. Bulychev; S. Ya. Knyazhanskii


Publisher
Springer
Year
1999
Tongue
English
Weight
455 KB
Volume
48
Category
Article
ISSN
1573-9171

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✍ Giuseppe Borsato; Ottorino De Lucchi; Fabrizio Fabris; Vittorio Lucchini; Marco 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 111 KB

The title compounds, new members in the class of tris-annelated benzenes with [2.2.1] bicyclic rings, were obtained in high yields by coupling of 2-bromo-3-trimethyltin-5,6-dimethylenenorborn-2-ene with copper(I) 2-thiophenecarboxylate (CuTC). The syn isomer was reacted with 3 equiv. of the dienophi