Treatment of the predissociation of the A1Σu+ state of As2 by the interaction with a repulsive state
✍ Scribed by G. Wannous; C. Effantin; F. Martin; J. d'Incan
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 457 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0022-2852
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📜 SIMILAR VOLUMES
Two mechanisms for the predissociation of the C 2X: state of N$ ar8 discussed -the accidentai mechanism nnd a direct, homogeneous process C -f B 'c:. The matrix elements for the latter channel are dominated by a contribution from the nuclear kinetic energy operator, containing a Fran&-Condon integra
The electronic non-diagonal Born-Oppenheimer coupling matrix elements between the molecular h?drogen DIE, state and the B' L Zu end B 1Z; u states were calculated in the Hartree-Fock approx-imztion at R= 1.0,1.2,1.6 and 2.0 au. These were used to calculate the predissociation widths for the v = 3 to