The predissociation of H2 molecules in the 3prr D ' KI", state has been studied by Farm-profile and~sis of the Rs have been measured. Stron, 0 indication of the opening of a new channel of dissociation is reported\\_ Coupling with the B"B t Z: state may be responsible for this.
Predissociation of the H2 D1Πu state
✍ Scribed by P.S. Julienne
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 229 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The electronic non-diagonal Born-Oppenheimer coupling matrix elements between the molecular h?drogen DIE, state and the B' L Zu end B 1Z; u states were calculated in the Hartree-Fock approx-imztion at R= 1.0,1.2,1.6 and 2.0 au. These were used to calculate the predissociation widths for the v = 3 to I2 levels of the D state with J = 1. The predissociation can only be caused by the 3' state. The widths are around 1 cm-l.
📜 SIMILAR VOLUMES
The optogalvanic spectrum and the emission spectrum of the highly excited Hz and Dz in a dc discharge have been investigated. Five bands of the triplet systems for Hz and D2 were observed in the region of 16130 to 17440 cm-': between the c 'II, state and the h 'Xl, g 'C: , i 'iI,, and j '4 states an