The electronic non-diagonal Born-Oppenheimer coupling matrix elements between the molecular h?drogen DIE, state and the B' L Zu end B 1Z; u states were calculated in the Hartree-Fock approx-imztion at R= 1.0,1.2,1.6 and 2.0 au. These were used to calculate the predissociation widths for the v = 3 to
A fano-profile study of the predissociation of the 3pπ D1Πu+ state of H2
✍ Scribed by M. Glass-Maujean; J. Breton; P.M. Guyon
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 443 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The predissociation of H2 molecules in the 3prr D ' KI", state has been studied by Farm-profile and~sis of the Rs have been measured. Stron, 0 indication of the opening of a new channel of dissociation is reported\_ Coupling with the B"B t Z: state may be responsible for this.
📜 SIMILAR VOLUMES
The predissociation probabilities of the rotational levels of the 4pn \*II: state for 8 vibrational bands are calculated using secoad-order perturbation theory. taking into secotint interference terms between the various dissochtike channels. The dt!duced predissociation yields agee welt v.ith the m
The optogalvanic spectrum and the emission spectrum of the highly excited Hz and Dz in a dc discharge have been investigated. Five bands of the triplet systems for Hz and D2 were observed in the region of 16130 to 17440 cm-': between the c 'II, state and the h 'Xl, g 'C: , i 'iI,, and j '4 states an
The transition probabilities for hydrogen D 3pn lll,(v'= 2 to 17) +X1 Z~(IJ" = 0) bands have been measured using synchrotron radiation\_ Good agreement is obtained with published theoretic -9 calculations.