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Calculation of the predissociation probabilities of the 4pπ1Π+uυ' ⩾ 1 levels of H2

✍ Scribed by M. Glass-Maujean

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
339 KB
Volume
68
Category
Article
ISSN
0009-2614

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✦ Synopsis

The predissociation probabilities of the rotational levels of the 4pn *II: state for 8 vibrational bands are calculated using secoad-order perturbation theory. taking into secotint interference terms between the various dissochtike channels. The dt!duced predissociation yields agee welt v.ith the measured yields throughout the vibrational series. This calculation gives US the tirst determination of the mdiatike lifetime of the 4p1; t fl state (7 f 1 ns) and of the predissociation probability of the -!p0 t--& < = 1 level (45 -c IA) x UP s'_

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