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Predissociation of the C2Σu+ state of N2+

✍ Scribed by Joel Tellinghuisen; D.L. Albritton

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
617 KB
Volume
31
Category
Article
ISSN
0009-2614

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✦ Synopsis

Two mechanisms for the predissociation of the C 2X: state of N$ ar8 discussed -the accidentai mechanism nnd a direct, homogeneous process C -f B 'c:. The matrix elements for the latter channel are dominated by a contribution from the nuclear kinetic energy operator, containing a Fran&-Condon integral of form (~la/aRlul).

📜 SIMILAR VOLUMES

Isotopic effects in accidental predissoc
Isotopic effects in accidental predissociation. The case of the C2Σ+u state of N+2
✍ A.J. Lorquet; J.C. Lorquet 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 534 KB

The large isotopic effect recently found in the decay of the C 'Cc state of Nf is interpreted by an indirect (accidental) predissociation mechanism. The C \*X; state interacts with a bound intermediate state, itself predissociated by a repulsive state. The competition between fluorescence and predis

Excited states of gaseous ions. Transiti
Excited states of gaseous ions. Transitions to and predissociation of the C2Σ+u state of n+2
✍ J.C. Lorquet; M. Desouter 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 470 KB

ii configuration interaction study of different electronic states of IQ; has been perkmned. The position in cncrsy and the refati;e $rtensity of the photoe!ectron bands of the "Zi 4 states has been calculated and cumpared ivith espariment. The C-X:, state is predissoc~te~ by a U, state, as previousl