Some ab initio calculations related to the predissociation of the C 2Σu+ state of N2+
✍ Scribed by A.L. Roche; H. Lefebvre-Brion
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 46 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
Two mechanisms for the predissociation of the C 2X: state of N$ ar8 discussed -the accidentai mechanism nnd a direct, homogeneous process C -f B 'c:. The matrix elements for the latter channel are dominated by a contribution from the nuclear kinetic energy operator, containing a Fran&-Condon integra
ii configuration interaction study of different electronic states of IQ; has been perkmned. The position in cncrsy and the refati;e $rtensity of the photoe!ectron bands of the "Zi 4 states has been calculated and cumpared ivith espariment. The C-X:, state is predissoc~te~ by a U, state, as previousl
The large isotopic effect recently found in the decay of the C 'Cc state of Nf is interpreted by an indirect (accidental) predissociation mechanism. The C \*X; state interacts with a bound intermediate state, itself predissociated by a repulsive state. The competition between fluorescence and predis