The general methods of testing thermodynamic data for binary solutions by the Gibbs-Duhem equation are briefly reviewed, and a new "composition-resolution " test is proposed. Thermodynamically exact methods of testing binary vapour-liquid equilibrium data, both for constant pressure and for constant
Treatment of binary Vapour-Liquid equilibrium data
✍ Scribed by S. Kemény; J. Manczinger
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 507 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0009-2509
No coin nor oath required. For personal study only.
✦ Synopsis
The results obtamed by mmmuzmg the sum of squares of dtierent functions of measured variables x, 1, y, P, wrth and wtthout weightmg are compared The unwelghted regressIon leads to different values of estimated parameters accordmg to the type of minimization cnterion It IS shown that the weighted regression of .x, t, y data gves rise to the same values of estimated parameters not dependmg on the type of mmmuzatlon cnterion Ttus IS also true for x, r, P data It LS shown that the simultaneous correlation of x, t, y, P data IS erroneous but ttus statement 1s valid only for "classical" treatment A very simple method IS proposed based on the concept of "multlresponse model" for treatment of all (x, t, y, P) data together
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