## Based on thermodynamic relationships and geometric concepts, a simple method is developed to interpolate isobaric or isothermal vapour-liquid equilibrium data of multicomponent systems. It is useful in reducing the amount of experimental work. Tests on five isobaric ternary systems indicate goo
Calculation of multicomponent vapour—liquid equilibrium from liquid boiling temperature data
✍ Scribed by Bogdan Jasiński; Stanisław Malanowski
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 582 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0009-2509
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✦ Synopsis
iterative numerical method has been suggested for calculating multicomponent vapourliquid equilibria from boiling temperature data involving minimization of temperature reciprocal residuals. For representation of the temperature as an implicit function of the liquid composition, the set of equations [7-131 is used. The Gram-Schmidt orthogonahzation is applied to overcome the singularity of the normal equations. Tests on four binary and one ternary system indicate very good agreement between the observed and calculated results.
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