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Transition-state conformations in the reductive opening of cyclopropyl methyl ketones

โœ Scribed by Dauben, William G.; Wolf, Richard E.


Book ID
126889823
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
917 KB
Volume
35
Category
Article
ISSN
0022-3263

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Reductive ring opening of cyclopropyl ke
โœ Yong Hae Kim; In Sang Lee ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 288 KB

## Functionalized cyclopropyl ketones have been found to undergo facile reductive cyclopropane ring opening with samarium (II) diiodide in the presence of a proton source. These reactions were exceedingly rapid, taking place in most cases at -78ยฐC under neutral conditions. An ester group substitut