𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reductive opening of acyclic conjugated cyclopropyl ketones with lithium in liquid ammonia

✍ Scribed by Dauben, William G.; Wolf, Richard Eugene.


Book ID
121450565
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
911 KB
Volume
35
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Reductive ring opening of cyclopropyl ke
✍ Yong Hae Kim; In Sang Lee πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 288 KB

## Functionalized cyclopropyl ketones have been found to undergo facile reductive cyclopropane ring opening with samarium (II) diiodide in the presence of a proton source. These reactions were exceedingly rapid, taking place in most cases at -78Β°C under neutral conditions. An ester group substitut

Reductive cleavage of 1-methyltricyclo[4
✍ Drury Caine; William R. Pennington; Troy L. Smith Jr. πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 288 KB

Reductive cleavage of the external(a.8) bond of the cyclopropane ring in tricyclo[x.y.O.O \*,x9\_ alkan-3-ones with lithium in liquid ammonia provides a general method of synthesis of spirocyclic ketones. \*,3 Piers and Worster have recognized that the stereochemical fate of the S carbon atom is an