Fluorescence intensity ratios in the A 1 P-X 1 S / band system of the CS radical, with £ Å 0-4, have been measured and analyzed using the r-centroid approximation. The radicals were generated in a microwave discharge and excited with laser radiation. Experimental branching ratios, together with Fran
Transition moment function, transition probabilities, and radiative lifetimes in the A 1Π–X 1Σ+ system of the CS molecule
✍ Scribed by Fernando R. Ornellas
- Book ID
- 108312616
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 175 KB
- Volume
- 296
- Category
- Article
- ISSN
- 0009-2614
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Transition probabilities for the B 1 + -X 1 + and the B 1 + -A 1 electronic systems are presented for v = 0-4 and J = 0-150 in each electronic state. The functional form of the electronic transition moment for the B-X transition is taken from published ab initio results. The B-A moment is assumed to
Accurate Born-Oppenheimer energies and adiabatic corrections are computed for the hydrogen molecule for the four lowest electronic states of 1 P u symmetry for internuclear distances, 0:5 6 R 6 100 bohr. Computed term values of the D 0 ð4pÞ 1 P À u state of D 2 compare favorably with experiment. The