Transition metal complexes of 13- and 14-membered N2O2macrocycles: synthesis and characterization
β Scribed by Omar S. M. Nasman
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 202 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0340-4285
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Benzoylacetic acid (1 tool) interacts with ethylenediamine or with propanediamine (2 tool) to yield new N 4 macrocycles 1,5,8,12-tetraazacyclotetradeca-2,4,9,11-tetraphenyl-3,10-dicarboxylic-4,11-diacetic acid-1,8-diene (L~) and 1,5,9,13-tetraazacyclohexadeca-2,4,10,12-tetraphenyl-3,11-dicarboxylic-
## dioxadiazacyclotetradecine derivatives The new vic-dioxime ligand 2 (LH4) carrying a 14-membered properties of tri-and pentanuclear complexes were investi- N202 macrocycle has been prepared. Mononuclear complex gated by cyclic voltammetry. For (LHJ2Cu3 two reduction wa-(LH3),Ni, trinuclear comp
Synthesis and Cu\*+-Complexes of a Series of 12-, 14-and 16-Membered cis-and trans -N,S,-Macroc ycles