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Transition metal complexes of 13–14-membered tetraazamacrocycles: Synthesis and characterization

✍ Scribed by Mohammad Shakir; Omar S.M. Nasman; Ajax K. Mohamed; Saji P. Varkey

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
299 KB
Volume
15
Category
Article
ISSN
0277-5387

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Metal complexes of macrocyclic ligands.
Metal complexes of macrocyclic ligands. Part XXIII. Synthesis, properties, and structures of mononuclear complexes with 12- and 14-membered tetraazamacrocycle-N,N′,N″,N‴-tetraacetic Acids
✍ Andreas Riesen; Margareta Zehnder; Thomas A. Kaden 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 German ⚖ 439 KB 👁 2 views

The two tetraazamacrocycle-N.N',N",N"'-tetraacetic acids H,dota and H,teta form with Ni2+, Cu2+, and Zn2+ (M") mononuclear complexes MLH, and M'[ML], M' being an alkaline earth ion. The structures of Ni(H2dota) and Cu(H,dota) have been solved by X-ray structure analysis. The metal ions are in a dist