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Synthesis and Complexation of a New 14-Membered N2O2 Macrocycle withvic-Dioxime Moieties

✍ Scribed by Hamuryudan, Esin ;Bekaro??lu, ÖZer


Publisher
Wiley (John Wiley & Sons)
Year
1994
Tongue
English
Weight
500 KB
Volume
127
Category
Article
ISSN
0009-2940

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✦ Synopsis


dioxadiazacyclotetradecine derivatives

The new vic-dioxime ligand 2 (LH4) carrying a 14-membered properties of tri-and pentanuclear complexes were investi- N202 macrocycle has been prepared. Mononuclear complex gated by cyclic voltammetry. For (LHJ2Cu3 two reduction wa-(LH3),Ni, trinuclear complexes (LH),Cu3, (LH),Co3, (LH),-ves appeared at 0.215 and -0.870 V. LzCu5(phen)2z Pd3, and ( L H ) , C O ~( ~~) ~C ~, , dinuclear complex (LH3)Z-exhibited four reduction waves at 0.200, -0.025, -0.670, and (UOz),(OH)z, and pentanuclear complex [ L , C ~~( p h e n ) ~] --1.170 V. (NO,), have been synthesized from LH4. The electrochemical 2 (LH4)


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