Synthesis and Cu\*+-Complexes of a Series of 12-, 14-and 16-Membered cis-and trans -N,S,-Macroc ycles
Synthesis and Complexation of a New 14-Membered N2O2 Macrocycle withvic-Dioxime Moieties
✍ Scribed by Hamuryudan, Esin ;Bekaro??lu, ÖZer
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1994
- Tongue
- English
- Weight
- 500 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0009-2940
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✦ Synopsis
dioxadiazacyclotetradecine derivatives
The new vic-dioxime ligand 2 (LH4) carrying a 14-membered properties of tri-and pentanuclear complexes were investi- N202 macrocycle has been prepared. Mononuclear complex gated by cyclic voltammetry. For (LHJ2Cu3 two reduction wa-(LH3),Ni, trinuclear complexes (LH),Cu3, (LH),Co3, (LH),-ves appeared at 0.215 and -0.870 V. LzCu5(phen)2z Pd3, and ( L H ) , C O ~( ~~) ~C ~, , dinuclear complex (LH3)Z-exhibited four reduction waves at 0.200, -0.025, -0.670, and (UOz),(OH)z, and pentanuclear complex [ L , C ~~( p h e n ) ~] --1.170 V. (NO,), have been synthesized from LH4. The electrochemical 2 (LH4)
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A new layered barium aluminate hydrate, BaAl 2 O 3 (OH) 2 ' H 2 O, has been synthesized from a hydrothermal system. The compound crystallizes in the orthorhombic space group