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Transannular polymerization of 1,5-cyclooctadiene

โœ Scribed by Reichel, Bernd ;Marvel, C. S. ;Greenley, R. Z.

Publisher
Wiley (John Wiley & Sons)
Year
1963
Tongue
English
Weight
442 KB
Volume
1
Category
Article
ISSN
0449-2951

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Cationic transannular polymerization of
Cationic transannular polymerization of 1,5-cyclooctadiene by Cp2MCl2 (M = Ti, Zr or Hf) ziegler-natta catalysts with Et3 Al, Et2 AlCl and Et3 Al2 Cl3 as cocatalysts
โœ Efthymios P. Bokaris; Michael G. Siskos; Antonios K. Zarkadis ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 302 KB

The cationic transannular polymerization of cis,cis-l,5-cyclooctadiene (COD) initiated by Ziegler-Natta catalysts of the type Cp2MCI: (M = Ti, Zr, HI) with various alkylaluminium compounds, such as Et3A1, Et2AIC1 and Et3A12CI 3, was studied. The order of activity of these catalysts depends on the me

Stereochemistry of cationic addition -ฯ€,
Stereochemistry of cationic addition -ฯ€,ฯ€ transannular cyclization of 1,5-cyclooctadiene
โœ I. Tabushi; K. Fujita; R. Oda ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 244 KB

The chemistry of carbonlum Ion stabilized by means of an acprouriately located'it-bond or, in some cases, of a c-bond has been remarkably advanced(l). The observed strong C+-'ilinteractlon suuaests that If an unconjuqated diene is treated wlth catlonic rea.qent, transannular cyclizatlon should take