Polymerization of butadiene, allene, and acetylene by (1,5-cyclooctadiene)-nickel halides
β Scribed by Porri, L. ;Gallazzi, M. C. ;Vitulli, G.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1967
- Tongue
- English
- Weight
- 162 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0449-2986
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π SIMILAR VOLUMES
The block copolymerization of allene derivatives (3A-3D) with 1,3-butadiene (2) by [(allyl)NiOCOCF 3 ] 2 (1) is described. For instance, the living coordination polymerization of phenylallene (3A, 50 equiv) starting from the living poly(2), which was prepared by the polymerization of 2 (160 equiv) b
Abatraet-In order to study the mechanism of polymerization of phenylacetylene initiated by rhodium catalysts, the polymerization of phenylacetylene was carried out in the presence of various substituted benzenes. It was found that the benzenes with electron donor substituents had little effect on th
The cationic transannular polymerization of cis,cis-l,5-cyclooctadiene (COD) initiated by Ziegler-Natta catalysts of the type Cp2MCI: (M = Ti, Zr, HI) with various alkylaluminium compounds, such as Et3A1, Et2AIC1 and Et3A12CI 3, was studied. The order of activity of these catalysts depends on the me