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Transannular hydride shifts in the bicyclo[3,3,1]nonane system

✍ Scribed by Eakin, M. A.; Martin, J.; Parker, W.

Book ID
121665123
Publisher
Royal Society of Chemistry
Year
1968
Weight
224 KB
Volume
6
Category
Article
ISSN
0009-241X

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πŸ“œ SIMILAR VOLUMES

Bicyclo[3.3.1]nonanes as synthetic inter
Bicyclo[3.3.1]nonanes as synthetic intermediates XIII. : Novel transannular hydride shifts enforced by relief of the steric constraint in the bicyclo[3.3.1]nonane system bearing endo-substituents at position 7
✍ Takefumi Momose; Toshiyuki Itooka; Takafumi Nishi; Mari Uchimoto; Keiko Ohnishi; πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 697 KB

The Huang-Minlon reduction of 7a-hydroxymethylbicyclo[3.3.11nonan-3-one (1) gave 7B-methylbicyclo[3.3.llnonan-36-01 (21, a product formed as a result of the transannular 1,6-hydride shift enforced by relief of the steric constraint in the system. Another example of the intramolecular hydride transfe