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A transannular 2,6-hydride shift in the bicyclo[3,3,1]nonane system

✍ Scribed by Parker, W.; Stevenson, J. R.

Book ID
120882774
Publisher
Royal Society of Chemistry
Year
1969
Weight
143 KB
Volume
21
Category
Article
ISSN
0577-6171

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πŸ“œ SIMILAR VOLUMES

Bicyclo[3.3.1]nonanes as synthetic inter
Bicyclo[3.3.1]nonanes as synthetic intermediates XIII. : Novel transannular hydride shifts enforced by relief of the steric constraint in the bicyclo[3.3.1]nonane system bearing endo-substituents at position 7
✍ Takefumi Momose; Toshiyuki Itooka; Takafumi Nishi; Mari Uchimoto; Keiko Ohnishi; πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 697 KB

The Huang-Minlon reduction of 7a-hydroxymethylbicyclo[3.3.11nonan-3-one (1) gave 7B-methylbicyclo[3.3.llnonan-36-01 (21, a product formed as a result of the transannular 1,6-hydride shift enforced by relief of the steric constraint in the system. Another example of the intramolecular hydride transfe