The Huang-Minlon reduction of 7a-hydroxymethylbicyclo[3.3.11nonan-3-one (1) gave 7B-methylbicyclo[3.3.llnonan-36-01 (21, a product formed as a result of the transannular 1,6-hydride shift enforced by relief of the steric constraint in the system. Another example of the intramolecular hydride transfe
✦ LIBER ✦
Studies on bicyclo[3.3.1]nonanes—II : Transannular hydride shifts in bridged bicycles
✍ Scribed by R.A. Appleton; J.R. Dixon; J.M. Evans; S.H. Graham
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 647 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4020
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## Abstract Carbon‐13 NMR spectra of solid polycrystalline bicyclo[3.3.1]nonan‐9‐one and adamantanone have been measured at 315K. The relatively narrow ^13^C linewidths observed for these solids, together with measured spin‐lattice relaxation times, indicate that both these solids are orientational