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Carbon-13 NMR spectra of solid bicyclo[3. 3. 1]nonan-9-one. Conformational studies in the solid state

✍ Scribed by Roderick E. Wasylishen; Kenneth J. Friesen

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
188 KB
Volume
13
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Carbon‐13 NMR spectra of solid polycrystalline bicyclo[3.3.1]nonan‐9‐one and adamantanone have been measured at 315K. The relatively narrow ^13^C linewidths observed for these solids, together with measured spin‐lattice relaxation times, indicate that both these solids are orientationally disordered. Observed ^13^C chemical shifts of solid bicyclo[3.3.1]nonan‐9‐one indicate a twin‐chair conformation for the two cyclohexanone rings.

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