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Transannular directive influences in electrophilic substitution of 2.2-paracyclophane

✍ Scribed by Reich, Hans J.; Cram, Donald J.


Book ID
125931973
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
376 KB
Volume
90
Category
Article
ISSN
0002-7863

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Transannular Hydride Migration in Pseudo
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## Abstract A vinylogous pinacol–pinacolone rearrangement is reported that takes place although the two hydroxyl groups are formally separated by seven bonds. It involves a transannular hydride shift that occurs between the benzylic positions of the __pseudo‐geminally__ substituted [2.2]paracycloph