Conformational Rigidity and Flexibility of the Paracyclophane Skeleton in Substituted [2.2]Paracyclophanes
✍ Scribed by Z. A. Starikova; I. V. Fedyanin; M. Yu. Antipin
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Tetraalkoxy‐substituted [2.2]paracyclophane‐1,9‐dienes can be prepared in three steps from dithia[3.3]paracyclophanes. A mixture of pseudo‐geminal and pseudo‐ortho diastereomers is produced and the pure compounds can be separated by fractional crystallization. The solid state structures