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Trans-halido, hydrido tetrakis(piperidine) iridium(III) complexes

โœ Scribed by Ernest R. Birnbaum

Book ID
118908350
Publisher
Elsevier Science
Year
1971
Weight
527 KB
Volume
33
Category
Article
ISSN
0022-1902

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A hydrido diolefin complex of iridium(II
A hydrido diolefin complex of iridium(III)
โœ S.D. Robinson; B.L. Shaw ๐Ÿ“‚ Article ๐Ÿ“… 1964 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 50 KB

Complexes containing hydrogen and an olefin bonded to the same metal atoms have been postulated as unstable intermediates in varioue catalytic reactions e.g. CXO syntheses (l), but have not hitherto been prepared. We now describe a hydrido cycle-octa-1,5-diene complex of iridium(II1) CI~c12(C#,2)12