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Trifluoromethyl and mixed hydrido trifluoromethyl complexes of iridium(III) as potential precursors of an iridium(I) trifluoromethyl complex

✍ Scribed by T.R. Greene; W.R. Roper

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
431 KB
Volume
299
Category
Article
ISSN
0022-328X

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## Abstract Four iridium complexes with achiral phosphino‐oxazoline (PHOX) ligands were readily prepared in two steps starting from commercially available phenyloxazolines. The air‐stable complexes with tetrakis[3,5‐bis(trifluoromethyl)phenyl]borate (BAr~F~) as counterion showed high reactivity in